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Ref.:&&Ms. No. WSPC-JAD-D-14-00005
Non-equilibrium thermodynamic theory of ferroelectric phase transitions
Journal of
Thanks for your submission to the Journal of
The manuscript entitled &Non-equilibrium thermodynamic theory of ferroelectric phase transitions& has been reviewed and the review comments are appended below. You will see that they are advising against publication of your work, therefore I couldn't recommend it for publication. If you dissent, please submit a rebuttal against each point or resubmit your work, we will reconsider our decision. :rol:
Thank you for giving us the opportunity to consider your work. I hope the outcome of this evaluation will not discourage you from the future contributions to this journal.
Yours sincerely
Managing Editor
Journal of
Reviewers' comments:
Reviewer #1: The manuscript is very strange. It consists of two parts and to describe what the first part is about let us read the Abstract: &First, the limitations of the classical thermodynamic theory of ferroelectric phase transition (known as the Landau-Devonshire theory) were reviewed critically. The unpleasant consequence caused by the metastable states hypothesis, and evidence for the non-existence of metastable states, i.e. the logical conflict?& This is quite enough to stop and to begin to ask questions.& &Begin with the &metastable states hypothesis&. If the authors consider existence of these states as a hypothesis I see no point to address to Landau and Devonshire. It would be logical to start with the van der Waals Thesis (1873), well before both Landau and Devonshire were born. One should be more serious when &reviewing critically& scientific concepts generally accepted during at least 150 years (I am not sure that van der Waals was the first). An experimental observation that so many people (millions without exaggeration) during so long time considered metastable states as reality and not as a hypothesis is also worth explanation, isn't it?&&The more that the &evidence for the non-existence of metastable states& is so simple according to the authors (p.3): if the&&&Gibbs energy& should be minimum the metastable states are excluded. How this is compatible with Fig.1, where this &Gibbs& energy has several minima is beyond my understanding.&&Apart from this it is just fantastic that according to the authors it was 150 years of massive blindness because such a trivial argument was overlooked.&&
It makes no sense to discuss the second part of the manuscript. It is accepted in a healthy scientific society that a new theory replacing an old one is discussed only after it is shown where and why the old theory was wrong or not sufficient. This is not the case of the present manuscript and it is pointless to discuss its second part. Therefor, I could not recommend its publishing.
Reviewer #2: Presented paper pretends to give a rather severe criticism of the well established concepts in Landay theory of the first order phase transitions. However, since the very beginning of the paper, arguments are not well formulated and visibly suggest that authors somehow lacks the common understanding to Landau theory. For example, authors try to demonstrate inconsistencies in calculations of&&stable/equilibrium state, but they do not really provide reader with precise assumptions and definitions of these terms, it requires a lots of imagination to guess what issues they actually have in mind.
Anyway, it is well known that phase coexistence near first order phase transition in solids is often realized by motion of interphase boundaries. This knowledge does not disqualify the concepts of the simplified single-phase Landau theory as given in textbooks, rather, the understanding of the real processes of first-order phase transition usually starts from estimation and the minimalization of the Laundau potential like in the equation (4), and simplest texbook analysis already does give an estimation thermodynamically possible (maximum, in a sense) range of the thermal hystheresis.
Therefore, this paper would make more confusion then benefit. I cannot recommend its publication.
Reviewer #3:&&This article is interesting and may be published after some changes. The main contents of the article are connected with application of non-equilibrium thermodynamics to area of a temperature hysteresis upon the ferroelectrics phase transitions of the first order. In this area the ferroelectric crystal is in the heterophase state which stability is defined by many factors. In this article the theory allow connecting among themselves action of various factors on a condition of a crystal is offered. Such theory certainly can be useful at creation in the ferroelectric crystals of handmade domain structure. Shortcomings are carelessly written Introduction and the Conclusion. Not clearly why in Introduction Landau-Devonshire theory is discussed. Whereas it is well known that this theory considers of phase transition of the first order as occurring instantly and is therefore inapplicable for the description of the physical phenomena observed in the area of heterophase state which actually and considers in the article. In the Conclusion it would be desirable to see more certain conclusions about possibility of application of the theory stated in article for an experiment explanation
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有谁见过？有谁吃过？
嘻嘻。看着不好看。吃起来到是好吃。
这是洗干净的，不洗真的拿不出来见人呀！旅顺这边没有看到，这是我们回到蓉蓉姥姥家吃到的，超便宜。放辣椒炖，那味绝了。
来说说他是什么吧！你吃过吗？
大连人叫海腚，海柿子，各个地方叫法不一。真实名字人家叫海葵！
口感很脆，做汤和炖这吃都可以。爆炒也行
海葵的外表很像植物，但其实是动物。海葵共有1000多种，栖息于世界各地的海洋中，从极地到热带、从潮间带到超过10000米的海底深处都有分布，而数量最多的还是在热带海域。暖海中的个体较大，呈圆柱形。在岩岸贮水的石缝中，常见体表具乳突的绿侧花海葵。在我国东海，太平洋侧花海葵数量之多每平方米可达数百至近万个。在几平方厘米的贝壳、石块上，也会有紫褐色带桔黄色纵带的纵条肌海葵，当其收缩时酷似西瓜又名西瓜海葵。
来几张漂亮的照片，大家就不会恶心了。
是不是海腚眼吗 ？
什么东东？？
海柿子，小时候吃过
看着像水母，哈哈，不知道是什么.
我们叫海腚，不知道学名是什么
海腚眼额。。。弄点小酒吧。
嘛玩意儿？俺一正宗大连人竟然木有见过，惭愧惭愧。。。
俗称海腚眼，学名某种海葵，哈哈，我记得欣蓉妈妈是开母婴店的对吗?不知道有没有记错。。。
俗称海腚眼，学名某种海葵，哈哈，我记得欣蓉妈妈是开母婴店的对吗?不知道有没有记错。。。
不是哦，我不开店，家庭主妇一个。
#6 Angle笑然
海腚眼额。。。弄点小酒吧。
味道绝了，鲜呀&&哈哈
#7 受伤的刺猬
嘛玩意儿？俺一正宗大连人竟然木有见过，惭愧惭愧。。。
大连没有卖的，卖的也少吧！
我们叫海腚，不知道学名是什么
大连应该都怎么叫吧！我们也叫还腚。
#4 小龙妞0708
看着像水母，哈哈，不知道是什么.
大笨蛋，大笨蛋
海柿子，小时候吃过
有的地方叫海柿子，嘻嘻
#1 小望孕妈妈
是不是海腚眼吗 ？
答对啦，送花拉，
不是哦，我不开店，家庭主妇一个。
那记错了，嘿嘿，欣蓉妈妈是旅顺哪里的，我也是家庭煮妇啊，有空可以一起溜达神马的，要不早晚被社会落下了。。。嘿嘿...
#16 NQlove
那记错了，嘿嘿，欣蓉妈妈是旅顺哪里的，我也是家庭煮妇啊，有空可以一起溜达神马的，要不早晚被社会落下了。。。嘿嘿...
我现在已经与世隔绝了，我在土城子这边。天天在家里，快长毛了。
#17 昕蓉妈
我现在已经与世隔绝了，我在土城子这边。天天在家里，快长毛了。
哈，离的有点远，我在旅顺开发区，我也快长毛了，现在孩子没生，生了就更没空了。。
#18 NQlove
哈，离的有点远，我在旅顺开发区，我也快长毛了，现在孩子没生，生了就更没空了。。
无聊呀!哎&&额的青春。
#7 受伤的刺猬
嘛玩意儿？俺一正宗大连人竟然木有见过，惭愧惭愧。。。
我也是。。第一次见，不是大连特产吧？
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